Medium Molecular Weight Nonionic Polyacrylamide

Medium Molecular Weight Nonionic Polyacrylamide

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PAMCHEM Medium Molecular Weight Nonionic Polyacrylamide (NPAM) is a synthetic water-soluble linear polymer with a non-ionic functional structure (degree of hydrolysis < 3.0%).
Category
Nonionic Polyacrylamide
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Description
Technical Parameters

Product Overview

 

 

PAMCHEM Medium Molecular Weight Nonionic Polyacrylamide (NPAM) is a synthetic water-soluble linear polymer with a non-ionic functional structure (degree of hydrolysis < 3.0%). Designed for industrial environments where high electrolyte concentrations, fluctuating pH, or multivalent ions cause ionic polymers to coil or precipitate, this grade relies on stable hydrogen-bonding adsorption. It provides controlled solution viscosity, preventing over-bridging while maintaining rapid particle-wetting characteristics in precision processing loops.

 

Medium Molecular Weight Grade Profile

 

 

Molecular Weight

8 - 12 Million Daltons (intrinsic viscosity method).

Ionic Character

Nonionic (Zero charge density; zeta potential approaching 0 mV).

Physical Form

Free-flowing white granular powder.

Bulk Density

0.65 - 0.75 g/cm³.

Dissolution Time

≤ 60 minutes (25°C, 0.1% concentration).

 

Flocculation & Dispersion Control

 

 

Nonionic polyacrylamide functions via multi-point hydrogen bonding and particle adsorption rather than electrostatic attraction.


Charge Neutrality: Polymer chains carry no electrical charge, maintaining performance during sudden fluctuations in total dissolved solids (TDS) or high salinity.


Shear Tolerance: Moderate chain length withstands mechanical turbulence in high-shear transfer lines and centrifugal dosing loops without excessive chain scission.

 

Technical Specifications

 

 

Parameter

Specification Limit

Test Method / Standard

Appearance

White granular powder

Visual Inspection

Solid Content

≥ 88.0%

Oven Drying (105°C, 2 hours)

Degree of Hydrolysis

< 3.0%

Potentiometric Titration

Solution Viscosity (0.1% at 25°C)

400 - 700 mPa·s

Brookfield LV Viscometer (Spindle 1, 60 rpm)

Residual Acrylamide Monomer

< 0.05% (500 ppm)

HPLC

 

Industrial Solid-Liquid Separation Applications

 

 

Acidic & High-Salinity Wastewater: Clarifying industrial effluents containing high concentrations of calcium, magnesium, or monovalent salts where charged polymers fail due to charge-shielding.


Hydrometallurgical Ore Slurries: Liquid-solid separation in acid leach circuits (gold, copper, zinc, and nickel extraction) requiring strict ionic stability.


Coal & Mineral Tailings: Centrifugal dewatering and settling of fine mineral suspensions, clay wash water, and silica slurries.


Paper Manufacturing: Serving as a non-ionic fiber dispersing agent and wet-end retention aid in neutral sizing paper machines.

 

Medium Vs. High Molecular Weight Nonionic PAM

 

 

Feature

Medium Molecular Weight

High Molecular Weight

Target Molecular Weight

8 - 12 Million Daltons

15 - 18 Million Daltons

0.1% Solution Viscosity

400 - 700 mPa·s

1500 - 3000+ mPa·s

Shear Tolerance

High (withstands pumping/turbulence)

Moderate (demands gentle handling)

Dissolution Speed

Faster; lower gel-blocking risk

Slower; requires extended aging time

Primary Industrial Function

Fine particle clarification, high-shear loops, dispersing

Aggressive sludge bridging, belt filter pressing

 

Grade Selection by Particle & Slurry Conditions

 

 

High Total Dissolved Solids (TDS > 15 g/L): Select medium molecular weight nonionic grades to bypass charge-shielding failure encountered by anionic polymers in saline process water.


Fine Suspended Solids (< 20 μm): Medium chain lengths provide adequate surface contact sites without trapping excess water into flocs.


Variable pH Loops (pH 3 - 9): Performance remains stable across acidic and neutral environments due to the absence of carboxylate groups.

 

Dissolution, Feed Preparation & Dosing

 

 

Makeup Water Quality: Use clean dilution water (15°C to 35°C) with hardness below 200 mg/L. Pre-filter iron-rich hard water.


Concentration Parameters: Maintain stock solutions between 0.1% and 0.5% weight/volume. Allow 45 to 60 minutes for complete hydration prior to secondary dilution at the injection point.


Agitation Equipment: Use a mechanical propeller stirrer running at 300 - 400 rpm in a polyethylene (PE) or 304 stainless steel tank. Avoid high-shear centrifugal pumps during makeup.

 

Production & Quality Consistency

 

 

Polymerization Method: Aqueous solution polymerization using high-purity acrylamide monomer with thermal initiation control.


Drying & Classification: Continuous fluidized-bed drying coupled with multi-stage air classification for a uniform particle size distribution (20 - 80 mesh).


Lot Verification: Every production run undergoes laboratory testing for intrinsic viscosity, residual monomer content, moisture, and dissolution rate. Retained samples are archived for 24 months.

 

Packaging & International Supply

 

 

Standard Packaging: 25 kg multi-layer kraft paper bags with inner polyethylene liners; 750 kg to 1000 kg FIBC bulk bags secured on export wooden pallets.


Marine Protection: Stretch-wrapped and heat-sealed with protective polyethylene hood film against moisture ingress.


Storage Environment: Store in dry warehouses (5°C - 30°C, relative humidity < 70%). Keep containers sealed to avoid caking.


Compliance Documentation: Manufactured in alignment with REACH pre-registration norms; supplied with batch-specific Certificates of Analysis (CoA) and GHS-compliant Safety Data Sheets (SDS).

 

FAQ

 

 

Q: Why select nonionic polyacrylamide over anionic alternatives in high-salinity water?

A: Nonionic polyacrylamide carries a zeta potential approaching 0 mV, meaning its chains lack charged groups subject to charge-shielding. In process streams rich in Ca²⁺ or Mg²⁺ ions, anionic polymers coil or precipitate, whereas nonionic grades maintain stable hydrogen-bonding adsorption onto suspended solids.

Q: How does medium molecular weight impact line pressure and metering pump performance?

A: Medium molecular weight grades produce lower solution viscosities (400 - 700 mPa·s at 0.1%) than ultra-high molecular weight variants. This minimizes friction loss in transfer pipework, prevents cavitation in diaphragm or progressive cavity pumps, and ensures stable active-polymer feed rates without pressure spikes.

Q: What causes undissolved gel particles ("fisheyes"), and how can they be prevented?

A: Fisheyes occur when dry powder is dumped too quickly or introduced into stagnant water, causing the particle exterior to hydrate instantly into a gel barrier trapping dry powder inside. Prevent this by feeding powder slowly through an automated induction funnel into the vortex of an agitated tank, keeping water temperature below 40°C.

Q: What is the verified shelf life under proper storage conditions?

A: When kept in unopened original packaging within a dry warehouse (< 30°C, relative humidity < 70%), the product maintains stable viscosity and performance for 24 months. Ambient moisture exposure induces caking and partial cross-linking, lowering active dissolution capacity.

Q: Does residual acrylamide monomer meet standard industrial discharge criteria?

A: Our standard grade contains less than 0.05% (500 ppm) residual acrylamide monomer. For operations subject to strict environmental discharge limits or potable water contact regulations, verification of local compliance standards is recommended.

 

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